Visualizing plating-induced cracking in lithium-anode solid-electrolyte cells

نویسندگان

چکیده

Lithium dendrite (filament) propagation through ceramic electrolytes, leading to short circuits at high rates of charge, is one the greatest barriers realizing high-energy-density all-solid-state lithium-anode batteries. Utilizing in situ X-ray computed tomography coupled with spatially mapped diffraction, cracks and lithium dendrites solid electrolyte have been tracked a Li/Li6PS5Cl/Li cell as function charge passed. On plating, cracking initiates spallation, conical ‘pothole’-like that form near surface plated electrode. The spallations predominantly electrode edges where local fields are high. Transverse then propagate from across stripped ingress drives spallation transverse by widening crack rear; is, front propagates ahead Li. As result, traverse entire before Li arrives other electrode, therefore circuit occurs.

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ژورنال

عنوان ژورنال: Nature Materials

سال: 2021

ISSN: ['1476-4660', '1476-1122']

DOI: https://doi.org/10.1038/s41563-021-00967-8